Technical Guides/Filter porosity

ISO 4793 · Sintered glass filters

Glass filter porosity, explained

Porosity grade is the single most important number on a sintered glass filter — and the one most often chosen wrongly. This guide covers what the grades mean, how to pick one, and how the European and American systems compare.

The basics

What a sintered filter actually is

A sintered (or fritted) glass filter is not a membrane with drilled holes. It is made by packing graded borosilicate glass particles into a mould and heating them until they fuse at their contact points without fully melting. What is left behind is a rigid disc threaded with an irregular, three-dimensional network of interconnected channels.

Because the channels are irregular, a filter cannot be given a single pore diameter. Instead it is classified by the maximum pore size — the largest channel that survives the manufacturing process, measured by a bubble-point test. That is the number the grade refers to.

The practical consequence matters: a grade P3 filter does not retain everything above 40 µm and pass everything below it. It retains reliably well above the maximum pore size, retains partially inside the stated range, and passes freely below the minimum.

SINTERED DISC — CROSS SECTION fused borosilicate grains, irregular channels ↓ flow path through the frit Channels are tortuous, not straight. This is why filters are rated by maximum pore size, not by a single nominal diameter.

Interactive

Filtration simulator

Pick a porosity grade and a particle size, and watch what the filter does with it.

0.3 µm500 µm

Result

Retained

 

P3 filtrate feed

Not to scale. Pore openings and particles are drawn on a shared logarithmic scale so that grades can be compared side by side in one frame.

Grades follow ISO 4793. Retention behaviour shown here is the general case for clean, rigid, roughly spherical particles — real performance depends on particle shape, concentration, compressibility and the filter cake that builds up during a run.

Reference

The ISO 4793 porosity grades

This is the system used throughout Europe and on all Synthware sintered glassware. The grade number runs from coarse to fine — a higher number means a finer filter.

GradeISO designationOlder markingMax. pore sizeWhat it is for
P0P250Por. 0160–250 µmCoarse filtration, gas dispersion, and as a support bed for a finer filter medium such as paper or a membrane.
P1P160Por. 1100–160 µmCoarse precipitates and gas dispersion where a high flow rate matters more than fine retention.
P2P100Por. 240–100 µmMedium and crystalline precipitates; washing of gases. The general-purpose workhorse grade.
P3P40Por. 316–40 µmAnalytical work with medium-sized precipitates. The most commonly stocked grade for Büchner and filter funnels.
P4P16Por. 410–16 µmAnalytical work with fine precipitates, and mercury filtration.
P5P1.6Por. 51.0–1.6 µmVery fine precipitates and bacterial filtration. Slow, and needs vacuum to run at a usable rate.

A coarser grade than P0 exists. Discs marked P500 (sometimes written P00, 250–500 µm) are made for gas sparging and as supports, where free flow matters far more than retention. They are not part of the common P0–P5 run and are ordered on request.

How the grades compare on one scale

125102050100200500 MAXIMUM PORE SIZE (µm, logarithmic) P500P0P1P2P3P4P5 250–500160–250100–16040–10016–4010–161.0–1.6

Note the gap. There is no standard ISO grade between 1.6 and 10 µm. If your separation sits in that window you are choosing between a P4 that will let some material through and a P5 that will run very slowly — or moving to a membrane on a P0 support.

Cross-reference

European grades vs. American descriptions

Glassware bought in North America is usually described in words — coarse, medium, fine — rather than by an ISO grade. The two systems were defined independently and do not line up cleanly.

ISO 4793 (Europe)Max. pore
P0 · P250160–250 µm
P1 · P160100–160 µm
P2 · P10040–100 µm
P3 · P4016–40 µm
P4 · P1610–16 µm
P5 · P1.61.0–1.6 µm
ASTM description (US)Pore size
Extra coarse170–220 µm
Coarse40–60 µm
Medium10–15 µm
Fine4–5.5 µm
Very fine2–2.5 µm
Ultra fine0.9–1.4 µm

Do not treat these as translations. American medium (10–15 µm) is close to European P4 (10–16 µm), not to P3 — even though P3 sits in the middle of the European range and is often called “medium” in conversation. If a published method specifies a filter in American terms, match it on the micron figure, not on the word.

CLEANING DIRECTION back-flush from below Solvent pushed the wrong way drives residue deeper.

Practical

Getting the most out of a frit

Wash a new filter before first use. Fresh sintered glassware carries loose glass dust from manufacturing. Draw dilute hydrochloric acid through it, then rinse thoroughly with distilled water, before anything analytical goes near it.

Always clean by back-flushing. Push solvent through from the stem side, against the direction of filtration. Rinsing from the top drives the retained solids further into the channels, where they set hard and permanently reduce the flow rate.

Match the cleaning agent to the residue. There is no universal solvent for a blocked frit, and the wrong one can set the blockage permanently.

ResidueApproach
Organic residues, greases and oilsA solvent the residue actually dissolves in, followed by acetone, then detergent and water.
Inorganic salts and mineral depositsA warm dilute acid soak, then a thorough rinse with distilled water.
Stubborn or unidentified depositsTime rather than force. A long soak clears far more than a stronger reagent, and costs you nothing if it fails.

Never use hydrofluoric acid, hot phosphoric acid, or strong hot alkali on a frit. All three attack borosilicate glass itself. All three attack borosilicate glass itself. They widen the pores instead of clearing them, so the disc no longer matches its stated grade.

Shop

Sintered glassware at Laboxin

Synthware filtration glassware is stocked across the standard porosity grades in borosilicate 3.3.